Preheat the oven to 350°F. Prepare three 8-inch round cake pans by greasing and flouring or lining them with parchment paper.
In a medium bowl, whisk together the flour, cocoa powder, baking soda, baking powder, and salt. Set aside.
In a large mixing bowl, beat the sugar and eggs on medium speed until light and fluffy, about 2–3 minutes.
Add the buttermilk, oil, and vanilla. Mix until fully combined.
Alternate adding the dry ingredients and warm coffee to the wet ingredients, mixing just until combined. Scrape the bowl and beat for one more minute.
Divide the batter evenly between the three pans (about 16 oz per pan).
Bake for 18–20 minutes, or until a toothpick inserted in the center comes out clean.
Let cakes cool in the pans for 20 minutes, then turn them out onto a wire rack to cool completely.